Gk. Nicolussi et al., MOLYBDENUM ISOTOPIC COMPOSITION OF INDIVIDUAL PRESOLAR SILICON-CARBIDE GRAINS FROM THE MURCHISON METEORITE, Geochimica et cosmochimica acta, 62(6), 1998, pp. 1093-1104
We report the isotopic composition of molybdenum in twenty-three preso
lar SiC grains from the Murchison meteorite which have been measured b
y resonant ionization mass spectrometry (RIMS). Relative to terrestria
l abundance land normalized to s-process-only Mo-96), the majority of
the analyzed grains show strong depletions in the p-process isotopes M
o-92 and Mo-94 and the r-process isotope Mo-100. Sixteen of these grai
ns have delta-values <-600% for these three isotopes. The observed iso
topic patterns of Mo from mainstream SiC grains clearly reveal the sig
nature of s-process nucleosynthesis. Three-isotope plots of all grain
data (delta(i)Mo vs. delta(92)Mo) show strong linear correlations with
characteristic slopes. This finding suggests mixing of solar-like mat
erial and pure s-process material in the parent stars. Comparison with
evolutionary calculations of nucleosynthesis and mixing in red giants
suggests that low-mass thermally-pulsed symptotic giant branch (TP-AG
B) stars are the most likely site for the observed s-process nucleosyn
thesis. Copyright (C) 1998 Elsevier Science Ltd.