CHELATING N-HETEROCYCLIC CARBENE LIGANDS IN PALLADIUM-CATALYZED HECK-TYPE REACTIONS

Citation
Wa. Herrmann et al., CHELATING N-HETEROCYCLIC CARBENE LIGANDS IN PALLADIUM-CATALYZED HECK-TYPE REACTIONS, Journal of organometallic chemistry, 557(1), 1998, pp. 93-96
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
557
Issue
1
Year of publication
1998
Pages
93 - 96
Database
ISI
SICI code
0022-328X(1998)557:1<93:CNCLIP>2.0.ZU;2-8
Abstract
A novel synthesis of palladium complexes with chelating N-heterocyclic carbene ligands is reported and direct proof is presented by X-ray di ffraction. These catalyst precursors are efficiently applied in pallad ium-catalyzed Heck-, Suzuki-and alkyne coupling reactions, demonstrati ng the versatility of our ligand concept in homogeneous catalysis. (C) 1998 Elsevier Science S.A. All rights reserved.