A. Kar et al., ORIGIN OF DIFFERENTIATED VOLCANIC AND PLUTONIC ROCKS FROM ASCENSION ISLAND, SOUTH ATLANTIC-OCEAN, Journal of Petrology, 39(5), 1998, pp. 1009-1024
The first phase of felsic magmatism on Ascension Island, in the Son of
trachyte and rhyolite domes, coulees, lava flows, and pyroclastic dep
osits, created the central and eastern parts of the island between abo
ut 1.0 and 0.56 my ago. The geochemical characteristics of the felsic
rocks are largely consistent with an origin by fractional crystallizat
ion of high Zr/Nb mafic magmas as evidenced by identical Nd-143/Nd-144
and similar Pb isotopic ratios. The high Zr/Nb basalt flows constitut
e one of the four distinct basalt and hawaiite suites identified from
Ascension bared on trace element characteristics. Syenite, monzonite,
and granite xenoliths associated with the felsic magmatism are interpr
eted as cumulate rocks from, and intrusive equivalents of, fractionati
ng felsic magmas. Many of the felsic rocks are characterized by high S
r-87/Sr-86 (>0.704) compared with mafic rocks (Sr-87/Sr-86 <0.703), ev
en when corrected for in situ decay of Rb-87 since eruption. Such hh S
r-87/Sr-86 coupled tenth high Nd-143/Nd-144 signatures do not correspo
nd to known suboceanic mantle reservoirs and in the most part appear t
o reflect sub-solidus addition of a high Sr-87/Sr-86 component. This c
omponent is probably a seawater-derived fluid that might be added at t
he surface from wind-blown spray, or more likely, at depth through hyd
rothermal circulation fluids with high Sr contents have been recovered
from fractures in a 3126-m-deep geothermal well). In either care, the
extremely low Sr contents of the felsic rocks make them particularly
susceptible to Sr-isotope modification. Internal (mineral) isochrons f
or two granite xenoliths give ages of similar to 0.9 and similar to 1.
2 Ma, with initial Sr-87/Sr-86 >0.705. Even though the high Sr-87/Sr-8
6 signature of mast of the volcanic rocks is demonstrably introduced a
fter solidification, the high initial Sr-87/Sr-86 values of the granit
e xenoliths suggest that hydrothermally altered pre-existing volcanic
basement may have been melted or assimilated during differentiation of
some of the felsic magmas.