SYNTHESIS AND CHARACTERIZATION OF THE FIRST E-UNIDENTATE [PH2P(O)NP(E)PH-2](-) METAL-COMPLEXES [AU(PH2P(O)NP(E)PH-2-E)(PH2P(O)NHPPH2)] AND [PD(PH2P(O)NP(E)PH-2-E)(2)(H2NCH2CH2NH2)] (E = S OR SE)

Authors
SLAWIN AMZ SMITH MB WOOLLINS JD
Citation
Amz. Slawin et al., SYNTHESIS AND CHARACTERIZATION OF THE FIRST E-UNIDENTATE [PH2P(O)NP(E)PH-2](-) METAL-COMPLEXES [AU(PH2P(O)NP(E)PH-2-E)(PH2P(O)NHPPH2)] AND [PD(PH2P(O)NP(E)PH-2-E)(2)(H2NCH2CH2NH2)] (E = S OR SE), Journal of the Chemical Society. Dalton transactions, (10), 1998, pp. 1537-1539
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
10
Year of publication
1998
Pages
1537 - 1539
Database
ISI
SICI code
0300-9246(1998):10<1537:SACOTF>2.0.ZU;2-1
Abstract
Chloride metathesis of[AuCl(HL)] [HL = Ph2P(O)NHPPh2] or [PdCl2(en)] ( en = ethane-1,2-diamine) in CH3OH with either 1 (or 2) equivalents of [Ph2P(O)NP(E)Ph-2](-) (E = S or Se) gave the neutral compounds [Au{Ph2 P(O)NP(E)Ph-2-E}(HL)] or [Pd{Ph2P(O)NP(E)Ph-2-E}(2)(en)] respectively; the anionic ligands in these complexes adopt a new bonding mode and f urthermore are involved in intramolecular N-H ... OP hydrogen bonding with HL or en.