SYNTHESIS AND CHARACTERIZATION OF THE AMINOCARBENE COMPLEXES [(ETA(5)-C5H5)FE(CO)(PPH3)(=C(NHR2)(CH2R1))]- [R-1 = H, ME OR PR R-2 = H, ME, ET, CHME2, CH2PH, CH(ME)PH, CH2CH=CH2 OR CH2CH2OH](BF4)

Authors
DAVIES SG EDWARDS AJ JONES S METZLER MR YANADA K YANADA R
Citation
Sg. Davies et al., SYNTHESIS AND CHARACTERIZATION OF THE AMINOCARBENE COMPLEXES [(ETA(5)-C5H5)FE(CO)(PPH3)(=C(NHR2)(CH2R1))]- [R-1 = H, ME OR PR R-2 = H, ME, ET, CHME2, CH2PH, CH(ME)PH, CH2CH=CH2 OR CH2CH2OH](BF4), Journal of the Chemical Society. Dalton transactions, (10), 1998, pp. 1587-1594
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
10
Year of publication
1998
Pages
1587 - 1594
Database
ISI
SICI code
0300-9246(1998):10<1587:SACOTA>2.0.ZU;2-1
Abstract
A number of secondary aminocarbenes of the type -[(eta(5)-C5H5)Fe(CO)( PPh3){=C(CH2R1)(NHR2)}]+BF4- were synthesised in very good yield [66-9 9%, R-1 = H, Me or Pr; R-2 = H, Me, Pt, CHMe2, CH2Ph, CH(Me)Ph, CH2CH= CH2 or CH2CH2OH]. The absolute configuration of one of the carbenes wa s established by a single-crystal X-ray diffraction experiment. The ch emistry of the carbene complexes was investigated.