Qm. Guo et K. Kato, THE EFFECT OF OPERATING-CONDITIONS ON SO2 REMOVAL IN SEMIDRY DESULFURIZATION PROCESS BY POWDER-PARTICLE SPOUTED BED, Kagaku kogaku ronbunshu, 24(2), 1998, pp. 279-284
A new type of semidry flue gas desulfurization (FGD) process without w
aste water treatment was developed with a powder-particle spouted bed
reactor. Fine sorbent powder slurries were continuously fed to a bench
scale experimental spouted bed in which coarse particles were fluidiz
ed. These slurries were fluidized and dried. SO2 sorbent was reacted w
ith SO2 gas and entrained from the bed and collected by bag filters. S
laked lime and slaked dolomite were used as SO2 sorbent. In this study
the effects of static bed height, superficial gas velocity, stoichiom
etric ratio of SO 2 in simulated gas to feeding sorbent, difference be
tween temperature of bed gas and wet bulb temperature of gas, that is,
approach to saturation temperature and medium particle size on SO2 re
moval, are investigated. Among these factors, the stoichiometric ratio
Ca/S and the approach to saturation temperature are the most importan
t factors. SO2 removal is significantly improved by reducing the appro
ach to saturation temperature. When the Ca/S ratio is greater than 1.2
and the approach to saturation temperature is less than 13 K, more th
an 95% SO2 removal is realized. In this experiment, the removal of SO2
increased with static bed height or decreased with superficial gas ve
locity. This is due to the longer apparent residence time of gas in th
e dense bed of particles. When coarse particles were normally fluidize
d in the spouted bed, the effect of the size of medium coarse particle
s in the bed on SO2 removal was not observed.