EFFECT OF SODIUM-IONS ON THE EXTRACTION OF RARE-EARTH-METALS BY LIQUID SURFACTANT MEMBRANES CONTAINING A CALIX[4]ARENE CARBOXYL DERIVATIVE

A novel host compound calixarene has been applied as a mobile carrier for the separation and concentration of rare earth metals by liquid su rfactant membranes (LSMs). Using the novel carrier, extraction of rare earth metals (Ho, Er and Y) by LSMs was systematically studied in a s tirred cell. Extraction behavior of rare earth metals by the carboxyl derivative of calix[4]arene was found to be extremely sensitive to coe xisting sodium ions in the feed solution. The extractability of rare e arth metals was remarkably enhanced by the addition of sodium ions. Th e permeation rate of rare earth metals through the LSMs in the presenc e of sodium ions was 100-fold higher than that without sodium ions. Th is enhancement of the permeation rate is attributed to the preferentia l conformation change in the host compound of calixarene initiated by sodium ions. The permeation mechanism of rare earth metals by LSMs is elucidated by an interfacial reaction model. (C) 1998 Elsevier Science B.V.