The mechanism of silicon epitaxy on porous Si(111) layers is investiga
ted by the Monte Carlo method. The Gilmer model of adatom diffusion ex
tended to the case of arbitrary surface morphology is used. Vacancies
and pendants of atoms are allowed in the generalized model, the activa
tion energy of a diffusion hop depends on the state of the neighboring
positions in the first and second coordination spheres, and neighbors
located outside the growing elementary layer are also taken into acco
unt. It is shown that in this model epitaxy occurs by the formation of
metastable nucleation centers at the edges of pores, followed by grow
th of the nucleation centers along the perimeter and the formation of
a thin, continuous pendant layer. Three-dimensional images of surface
layers at different stages of epitaxy were obtained. The dependence of
the kinetics of the epitaxy process on the amount of deposited silico
n is determined for different substrate porosities. (C) 1998 American
Institute of Physics.