CONDUCTOMETRIC STUDY OF LICLO4 AND BU4NBPH4 IN PROPYLENE CARBONATE TOLUENE MIXTURES

Citation
G. Moumouzias et G. Ritzoulis, CONDUCTOMETRIC STUDY OF LICLO4 AND BU4NBPH4 IN PROPYLENE CARBONATE TOLUENE MIXTURES, Berichte der Bunsengesellschaft fur Physikalische Chemie, 102(5), 1998, pp. 786-791
Citations number
46
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
ISSN journal
00059021 → ACNP
Volume
102
Issue
5
Year of publication
1998
Pages
786 - 791
Database
ISI
SICI code
0005-9021(1998)102:5<786:CSOLAB>2.0.ZU;2-Q
Abstract
The electrolytic conductances of LiClO4 and Bu4NBPh4 in Propylene carb onate-Toluene mixtures at 25, 30 and 35 degrees C have been measured. Limiting equivalent conductance, association constant and distance par ameter of ions were calculated by means of Lee-Wheaten equation. Gibbs energy of ion-pair formation due to non-Coulombic interaction, conduc tive transport activation energy, Walden product and Stokes radius are also evaluated.