SYNTHESIS AND CHARACTERIZATION OF TETRAALKYLAMMONIUM THIOMOLYBDATES AND THIOTUNGSTATES IN AQUEOUS-SOLUTION

Authors
ALONSO G AGUIRRE G RIVERO IA FUENTES S
Citation
G. Alonso et al., SYNTHESIS AND CHARACTERIZATION OF TETRAALKYLAMMONIUM THIOMOLYBDATES AND THIOTUNGSTATES IN AQUEOUS-SOLUTION, Inorganica Chimica Acta, 274(1), 1998, pp. 108-110
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
274
Issue
1
Year of publication
1998
Pages
108 - 110
Database
ISI
SICI code
0020-1693(1998)274:1<108:SACOTT>2.0.ZU;2-F
Abstract
An improved method for the preparation of (R4N)(2)MS4 (R= Me, Bu and M = Mo, W) is reported. The rapid substitution of the (NH4)(+) salts to [(Me)(4)N](+) and [(Bu)(4)N](+) salts, via reaction with aqueous (Me) (4)NCl and (Bu)(4)NBr is described. Thiometallates characterization by Fourier transform IR, W and NMR spectroscopies is reported. (C) 1998 Elsevier Science S.A. All rights reserved.