THERMAL-CONDUCTIVITY OF POLYCRYSTALLINE YBA2CU4O8

We have measured the thermal condUCtiVity K and the thermal diffusivit y a of a dense bulk ceramic polycrystalline sample of YBa2Cu4O8 (1:2:4 ) in the temperature range 30-300 K. We find kappa almost-equal-to 10 W m-1 K-1 at 100 K, significantly higher than in ceramic YBa2Cu3O7-del ta (1:2:3) and approaching the in-plane value for single-crystal 1:2:3 , and decreasing to 7.6 W m-1 K-1 at 300 K. The data for this sample c an be described by standard theories for phonon thermal conductivity o f crystalline materials with boundary, phonon, and electron scattering . The higher kappa in 1:2:4 as compared to 1:2:3 is, in this model, du e to the smaller point defect scattering in the former. The fitted par ameters for the three scattering mechanisms all agree with independent estimates based on simple models; inserting data for electric resisti vity, grain size, carrier density, and lattice properties we can predi ct kappa and its T dependence to within about 20%. We also discuss mod els for the phonon and electron thermal conductivities in some detail, including some second-order effects such as inelastic electron scatte ring and a T-dependent carrier density.