Crystal-field transitions within the H-3(4) multiplet of Pr3+ in Pr2Cu
O4 were studied by Raman scattering as a function of temperature. We o
bserved three crystal-field excitations at 156, 540, and 675 cm-1. The
peak at 156 cm-1, assigned by other authors to the lowest E(g) phonon
mode, shows a thermal broadening of the linewidth, which is the signa
ture for acoustic-phonon-relaxation processes between crystal-field le
vels. Our results are in excellent agreement with recent inelastic neu
tron-scattering experiments in Pr2CuO4.