SYNTHESIS AND CHARACTERIZATION OF THE PERIODATO COMPLEXES OF THORIUM(IV) - (MTH)-TH-I(H2IO6)(OH)(2)CENTER-DOT-4 H2O

Citation
Y. Yang et al., SYNTHESIS AND CHARACTERIZATION OF THE PERIODATO COMPLEXES OF THORIUM(IV) - (MTH)-TH-I(H2IO6)(OH)(2)CENTER-DOT-4 H2O, Radiochimica Acta, 80(3), 1998, pp. 147-150
Citations number
16
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00338230
Volume
80
Issue
3
Year of publication
1998
Pages
147 - 150
Database
ISI
SICI code
0033-8230(1998)80:3<147:SACOTP>2.0.ZU;2-Y
Abstract
Novel complexes of tetravalent thorium with periodate have been prepar ed from aqueous caustic potash solution. Chemical analysis indicates t hat the composition of these complexes possess the formula: (MTh)-Th-I (H2IO6)(OH)(2).4 H2O (M-I = Na+, K+, NH4+), and the complexes have bee n characterized by means of IR, Raman, W-vis spectra and thermal analy sis.