A 2ND-GENERATION TRANSITION METALLO-CARBONYL REAGENT FOR PROTEIN LABELING BASED ON THE TA(5)-CYCLOPENTADIENYL)FE(CO)(2)(ETA(1)-N-IMIDATO) SYSTEM

Authors
RUDOLF B ZAKRZEWSKI J SALMAIN M JAOUEN G
Citation
B. Rudolf et al., A 2ND-GENERATION TRANSITION METALLO-CARBONYL REAGENT FOR PROTEIN LABELING BASED ON THE TA(5)-CYCLOPENTADIENYL)FE(CO)(2)(ETA(1)-N-IMIDATO) SYSTEM, Tetrahedron letters, 39(24), 1998, pp. 4281-4282
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
24
Year of publication
1998
Pages
4281 - 4282
Database
ISI
SICI code
0040-4039(1998)39:24<4281:A2TMRF>2.0.ZU;2-A
Abstract
Complex (eta(5)-Cp)Fe(CO)eta(1)-N-imidato) is shown to be the basis of a new family of IR-detectable reagents for the controlled selective l abelling of biomolecules. One example of an N-succinimidyl ester is re ported here together with its reactivity with a model protein. (C) 199 8 Elsevier Science Ltd. All rights reserved.