Ws. Wang et Ks. Hwang, THE EFFECT OF TUNGSTEN PARTICLE-SIZE ON THE PROCESSING AND PROPERTIESOF INFILTRATED W-CU COMPACTS, Metallurgical and materials transactions. A, Physical metallurgy andmaterials science, 29(5), 1998, pp. 1509-1516
Three tungsten powders with average particle sizes of 8.7, 23.2, and 6
5.2 mu m were used to make W-15Cu compacts. The compacting pressure an
d sintering temperature were adjusted for each powder to attain the de
sired skeleton density. Sintered skeletons were then infiltrated with
oxygen-free copper at 1200 degrees C in hydrogen and in vacuum. Result
s showed that as the tungsten particle size decreased, higher compacti
ng pressures and sintering temperatures were required for the same des
ired skeleton density. The processing parameters and the tungsten part
icle size caused variations in the amount of closed pores and the W-W
contiguity, which in turn resulted in different infiltrated densities
and resistivities. Direct infiltration on green compacts was also exam
ined, and higher infiltration densities and lower electrical resistivi
ties were obtained compared to those obtained by infiltrating sintered
compacts. These results are discussed based on infiltrated density, d
ifferences in microstructure, and the W-W contiguity.