THE COCL2 PH(ET)(2)N-BH3/CO SYSTEM - REACTIONS OF THE BORANE AND COBALT CARBONYL SPECIES/

Authors
RAO MLN PERIASAMY M
Citation
Mln. Rao et M. Periasamy, THE COCL2 PH(ET)(2)N-BH3/CO SYSTEM - REACTIONS OF THE BORANE AND COBALT CARBONYL SPECIES/, Journal of organometallic chemistry, 553(1-2), 1998, pp. 91-97
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
553
Issue
1-2
Year of publication
1998
Pages
91 - 97
Database
ISI
SICI code
0022-328X(1998)553:1-2<91:TCPS-R>2.0.ZU;2-C
Abstract
The CoCl2/Ph(Et)(2)N:BH3/CO system is useful for the hydroboration and carbonylation of alkenes to obtain the corresponding dialkyl ketones. The cobalt carbonyl species formed in situ in this way is also useful for hydroacylation-cyclisation of norbornene and for the Pauson-Khand reaction. (C) 1998 Elsevier Science S.A.