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ENG

FIXATION OF TRIRUTHENIUM CLUSTERS ON MELAMINE - SYNTHESIS AND STRUCTURE OF U-3(MU(2)-H)(CO)(9)(MU(3),ETA(2)-NHC3N3(NH2)(2))], CIS-[(RU-3(MU(2)-H)(CO)(9))(2)(MU(3),ETA(2) MU(3),ETA(2)-NHC3N3(NH2))] AND O)(9))(2)(MU(3),ETA(2)/MU(3),ETA(2)-NHC3N3(NH2))]/

Authors

DORTA R STOECKLIEVANS H BODENSIECK U SUSSFINK G

Citation

R. Dorta et al., FIXATION OF TRIRUTHENIUM CLUSTERS ON MELAMINE - SYNTHESIS AND STRUCTURE OF U-3(MU(2)-H)(CO)(9)(MU(3),ETA(2)-NHC3N3(NH2)(2))], CIS-[(RU-3(MU(2)-H)(CO)(9))(2)(MU(3),ETA(2) MU(3),ETA(2)-NHC3N3(NH2))] AND O)(9))(2)(MU(3),ETA(2)/MU(3),ETA(2)-NHC3N3(NH2))]/, Journal of organometallic chemistry, 553(1-2), 1998, pp. 307-315

Citations number

Categorie Soggetti

Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear

Journal title

Journal of organometallic chemistry → ACNP

ISSN journal

0022328X

Volume

553

Issue

1-2

Year of publication

1998

Pages

307 - 315

Database

ISI

SICI code

0022-328X(1998)553:1-2<307:FOTCOM>2.0.ZU;2-S

Abstract

Melamine, C3N3(NH2)(3), was found to react with [Ru-3(CO)(12)] to give , with N-H activation, the monometallated derivative Ru-3(mu(2)-H)(CO) (9){mu(3),eta(2)-NHC3N3(NH2)(2)}] (1) and the two isomeric bimetallate d derivatives cis-[{Ru-3(mu-H)(CO)(9)}(2){mu(3),eta(2) : mu(3),eta(2) - NHC3N3(NH2)}] (cis-2) and trans-[{Ru-3(mu-H)(CO)(9)}(2){mu(3),eta(2) : mu(3),eta(2)-NHC3N3(NH2)}] (trans-2). The molecular structures of 1 , cis-2 and trans-2 have been determined by single-crystal X-ray cryst allography. (C) 1998 Elsevier Science S.A.