ELECTRONIC-SPECTRUM AND CRYSTAL-STRUCTURE OF FAC-MOOCL3(DPPE)

Authors
ISOVITSCH RA FRONCZEK FR MAVERICK AW
Citation
Ra. Isovitsch et al., ELECTRONIC-SPECTRUM AND CRYSTAL-STRUCTURE OF FAC-MOOCL3(DPPE), Polyhedron, 17(10), 1998, pp. 1617-1620
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
10
Year of publication
1998
Pages
1617 - 1620
Database
ISI
SICI code
0277-5387(1998)17:10<1617:EACOF>2.0.ZU;2-G
Abstract
X-ray analysis of the oxomolybdenum(V) complex MoOCl3(dppe) (dppe = 1, 2-bis(diphenylphosphino)ethane) shows that it is the facial isomer. (C 26H24Cl3MoOP2, space group P2(1)/n, a = 13.217(1), b = 12.8935(8), c = 16.0578(9) Angstrom, beta = 99.967(5)degrees, V = 2695.1(6) Angstrom( 3), Z = 4, R = 0.038 for 6228 data with I > 1 sigma(I).) The electroni c absorption spectrum of the title compound is also compared with thos e of other oxomolybdenum(V) complexes. (C) 1998 Elsevier Science Ltd. All rights reserved.