STRUCTURE, SPECTRAL AND MAGNETIC BEHAVIORS OF TETRAKIS(FLUFENAMATO)(CAFFEINE)(AQUA)DICOPPER(II) - FIRST EXAMPLE OF 2 NONEQUIVALENT LIGANDS AT THE APEX

Authors
MELNIK M KOMAN M GLOWIAK T
Citation
M. Melnik et al., STRUCTURE, SPECTRAL AND MAGNETIC BEHAVIORS OF TETRAKIS(FLUFENAMATO)(CAFFEINE)(AQUA)DICOPPER(II) - FIRST EXAMPLE OF 2 NONEQUIVALENT LIGANDS AT THE APEX, Polyhedron, 17(10), 1998, pp. 1767-1771
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
10
Year of publication
1998
Pages
1767 - 1771
Database
ISI
SICI code
0277-5387(1998)17:10<1767:SSAMBO>2.0.ZU;2-9
Abstract
The crystal and molecular structure of the tetrakis(flufenamato)(caffe ine)(aqua)dicopper(II) Cu-2(fluf)(4)(caf)(H2O), was determined by dire ct methods and Fourier techniques. The two copper(II) atoms are bridge d by four carboxylate group, with the apical ligand of a water molecul e around Cu(1), and a caffeine molecule around Cu(2). The spectral and magnetic properties are also discussed. (C) 1998 Elsevier Science Ltd . All rights reserved.