MESO-TETRAALKYNYLPORPHYRINS

5,10,15,20-Tetra(4-n-butylphenylethynyl) has been synthesised from 4-n -butylphenylpropynal and converted into its zinc(II) and lead(II) comp lexes. The solution electronic spectra of these porphyrins are compare d to the analogous complexes of 5,10,15,20-tetra(trimethylsilylethynyl )porphyrin. The aryl rings of the tetra(4-n-butylphenylethynyl)porphyr in extend the porphyrin chromophore, resulting in an increase in the o scillator strength and a bathochromic shift of about 600 cm(-1) in all the absorption bands. Metallation with lead(II) results in a larger b athochromic shift of about 1400 cm(-1), when compared with zinc(II), T he crystal structure of the pyridine zinc complex of 5,10,15,20-tetra( 4-butylphenylethynyl)porphyrin shows that the molecule has a large app roximately planar pi-system. Pairs of diagonally off-set pi-pi stacked porphyrins pack into a layer structure. Each pyridine ligand is locat ed in a pocket defined by four butyl chains.