SUPRAMOLECULAR SELF-ASSEMBLY IN TRIPHENYLLEAD(IV) DIMETHYLPHOSPHINODITHIOATE, (1)(X)[PH3PBS2PME2], A CHAIN POLYMER BUILT THROUGH INTERMOLECULAR PB-CENTER-DOT-CENTER-DOT-CENTER-DOT-S SECONDARY BONDS

Authors
EDELMANN FT HAIDUC I SILVESTRU C SCHMIDT HG NOLTEMEYER M
Citation
Ft. Edelmann et al., SUPRAMOLECULAR SELF-ASSEMBLY IN TRIPHENYLLEAD(IV) DIMETHYLPHOSPHINODITHIOATE, (1)(X)[PH3PBS2PME2], A CHAIN POLYMER BUILT THROUGH INTERMOLECULAR PB-CENTER-DOT-CENTER-DOT-CENTER-DOT-S SECONDARY BONDS, Polyhedron, 17(11-12), 1998, pp. 2043-2047
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
17
Issue
11-12
Year of publication
1998
Pages
2043 - 2047
Database
ISI
SICI code
0277-5387(1998)17:11-12<2043:SSITD>2.0.ZU;2-M
Abstract
0The first structural characterization of an organolead phosphinodithi oate is reported. According to an X-ray diffraction study, the title c ompound triphenyllead(IV) dimethylphosphinodithioate, (1)(x)[Ph3PbS2PM e2], forms a linear polymer in the solid state. Supramolecular associa tion through secondary bonds of the type P=S ... Pb leads to a polymer ic chain formed by -Pb-S-P=S ... Pb- units. The inorganic backbone is wrapped in a lipophilic ''hose'' made up of methyl and phenyl groups. (C) 1998 Elsevier Science Ltd. All rights reserved.