SIMULATION AND ANALYSIS OF FREE-RADICAL BRANCHING COPOLYMERIZATION KINETICS

Typical branching copolymerization is discussed. From the connotation regularity of relevant functions of variables, a curve model of Tcheby cheff meaning is simulated in Euclidean space and then homopolymerizat ion is approached in copolymerization so that the variation regularity of branching monomer concentration can be obtained. By this method, t he most realistic description of monomer variation is obtained from da ta processing of regression and simulation. On the basis of this work, branching initiation is handled. Then vector analysis is introduced i nto chain propagation in linear space of n dimensions. Laplace transfo rm is utilized for recurring, and the dynamic formula of branching cha in propagation, including chain transfer,is inferred. As a result, a s eries of microscopic information of branching kinetics can be obtained .