CHARACTERIZATION OF CATALYSTS SUPPORTED O N POLYMERS

Authors
Citation
R. Fisera et M. Kralik, CHARACTERIZATION OF CATALYSTS SUPPORTED O N POLYMERS, Chemicke listy, 92(5), 1998, pp. 395-401
Citations number
51
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00092770
Volume
92
Issue
5
Year of publication
1998
Pages
395 - 401
Database
ISI
SICI code
0009-2770(1998)92:5<395:COCSON>2.0.ZU;2-8
Abstract
A review concerns characterization of the catalysts based on polymers and compares them with inorganic catalysts. Characterization of microp orous polymer catalysts exploited in liquid-phase systems is mainly di scussed. Special attention is paid to the combination of methods for t he description of mobilities molecules inside the polymer, e.g., to th e evaluation of ''nanoscopic'' morphology from ISEC data, rotational m obility calculated from EPR measurements of a probe confined in the sw ollen polymer, and self-diffusion coefficients estimated from spin-ech o NMR with a steady-state gradient of the superposed magnetic field. T he consistency of obtained quantities with the catalytic activity is a lso discussed.