Electron-momentum spectroscopy based on the (e,2e) reaction has been u
sed to observe the energy-momentum density of valence electrons in the
[110] direction for an ultrathin, free-standing film of crystalline s
ilicon. An asymmetric scattering geometry is used in which the inciden
t, scattered and ejected electron energies are 20.8, 19.6, and 1.2 keV
, respectively. The measurement is complicated by the possibility of d
iffraction of the free electrons. The theory of the reaction including
diffraction is summarized and applied to experiments with different t
arget orientations. The orientation is determined from an independent
electron diffraction experiment. Very good agreement between theory an
d experiment is observed.