MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - [PTME2(PME2PH)(2)] AS A CLUSTER METALLATING AGENT - ISOLATION AND CHARACTERIZATION OF 19-VERTEX [(PME2PH)HPT-ETA(4)-SYN-B18H19(PME2PH)] AND 18-VERTEX [(PME2PH)(2)PTS2B15H14(NHCOME]

Authors
KAUR P BROWNLESS A PERERA SD COOKE PA JELINEK T KENNEDY JD STIBR B THORNTONPETT M
Citation
P. Kaur et al., MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - [PTME2(PME2PH)(2)] AS A CLUSTER METALLATING AGENT - ISOLATION AND CHARACTERIZATION OF 19-VERTEX [(PME2PH)HPT-ETA(4)-SYN-B18H19(PME2PH)] AND 18-VERTEX [(PME2PH)(2)PTS2B15H14(NHCOME], Journal of organometallic chemistry, 557(2), 1998, pp. 181-185
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
557
Issue
2
Year of publication
1998
Pages
181 - 185
Database
ISI
SICI code
0022-328X(1998)557:2<181:MBCC-[>2.0.ZU;2-Z
Abstract
[PtMe2(PMe2Ph)(2)] reacts quantitatively with [nido-B10H14], [arachno- 4-SB8H12] and [nido-7-SB10H12] to give [(PMe2Ph)(2)PtB10H12], [(PMe2Ph )(2)PtSB8H10] and [(PMe2Ph)(2)PtSB10H10]. With [syn-B18H22] it gives n ineteen-vertex [(PMe2Ph)HPtn(4)-syn-B18H19(PMe2Ph)](1) and only smalle r amounts of [(PMe2Ph)(2)Pt-n(4)-syn-B18H20], whereas with [(anti)-9,9 '-S2B16H16] a complex product mixture is generated from which eighteen -vertex [(PMe2Ph)(2)Pts(2)B(15)H(14)(NHCOMe)](1) is isolatable after t reatment with MeCN in air. (C) 1998 Elsevier Science S.A. All rights r eserved.