Unprecedented use of Si-29 NMR spectroscopy for a convenient determinationof enantiomeric excesses of chiral alpha-C-silylated amines and alcohols

Authors
Fortis, F Barbe, B Petraud, M Picard, JP
Citation
F. Fortis et al., Unprecedented use of Si-29 NMR spectroscopy for a convenient determinationof enantiomeric excesses of chiral alpha-C-silylated amines and alcohols, CHEM COMMUN, (6), 1999, pp. 527-528
Citations number
31
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
6
Year of publication
1999
Pages
527 - 528
Database
ISI
SICI code
1359-7345(19990321):6<527:UUOSNS>2.0.ZU;2-Q
Abstract
The use of routine refocused-decoupled INEPT Si-29 NMR spectroscopy, in the presence of the chiral lanthanide shift reagent Eu(tfc)(3), allows conveni ent enantiomeric excess determination of chiral alpha-C-silylated amines an d alcohols for the first time.