Lifting the lid on metatungstate. H-1 and W-183 NMR study of the six electron reduced anion [(H)(2){W-3(IV)(OH2)(3)}(W9O34)-O-VI(OH)(3)](3-)

Citation
C. Boskovic et al., Lifting the lid on metatungstate. H-1 and W-183 NMR study of the six electron reduced anion [(H)(2){W-3(IV)(OH2)(3)}(W9O34)-O-VI(OH)(3)](3-), CHEM COMMUN, (6), 1999, pp. 533-534
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
6
Year of publication
1999
Pages
533 - 534
Database
ISI
SICI code
1359-7345(19990321):6<533:LTLOMH>2.0.ZU;2-E
Abstract
The distribution of the eleven protons present in a six-electron reduced fo rm of metatungstate, [(H)(2){W-3(IV)-(OH2)(3)}(W9O34)-O-VI(OH)(3)](3-), in dry CD3CN is mapped by H-1 and W-183 NMR, allowing assessment of structural changes which accompany reduction.