STUDY OF THE TELOMERIZATION REACTION OF A CATIONIC SURFACTANT MONOMER

Authors
BOUTEVIN B ROBIN JJ BOYER B ROQUE JP SENHAJI O
Citation
B. Boutevin et al., STUDY OF THE TELOMERIZATION REACTION OF A CATIONIC SURFACTANT MONOMER, Macromolecular chemistry and physics, 195(1), 1994, pp. 129-137
Citations number
21
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular chemistry and physics → ACNP
ISSN journal
10221352
Volume
195
Issue
1
Year of publication
1994
Pages
129 - 137
Database
ISI
SICI code
1022-1352(1994)195:1<129:SOTTRO>2.0.ZU;2-Y
Abstract
A polymerizable methacrylic surfactant is synthetized from methacryloy l chloride and 11-bromoundecanol. The obtained cationic monomer is tel omerized with a fluorinated thiol, and the transfer constant C(T) is c alculated. This value is in the same range as transfer constants of cl assical methacrylic monomers. The obtained k(p)2/k(T) is low because o f the long chain ester. Polymers were prepared in homogeneous solution with an average molecular weight of 25000.