Cyclialkylation of arylalkyl epoxides with solid acid catalysts

Citation
Ja. Elings et al., Cyclialkylation of arylalkyl epoxides with solid acid catalysts, EUR J ORG C, (4), 1999, pp. 837-846
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
4
Year of publication
1999
Pages
837 - 846
Database
ISI
SICI code
1434-193X(199904):4<837:COAEWS>2.0.ZU;2-Y
Abstract
Solid acids, such as zeolites and clays, catalyse the intramolecular hydrox yalkylation (cyclialkylation) of several arylalkyl epoxides in moderate to excellent conversions and selectivities. The use of solid acids in these cy clialkylations provides a cleaner, better alternative to conventional Lewis and Bronsted acids, enabling a more facile workup of reaction mixtures and , in several cases, better selectivities.