Electrochemically generated tetraethylammonium peroxydicarbonate (TEAPC) an
d tetraethylammonium carbonate (TEAC) react under very mild conditions with
pyrroles affording, after addition of a suitable alkylating agent, the cor
responding N-alkylated pyrroles in high yields. C-Alkylated pyrroles have n
ot been isolated in any case reported.