Aggregation of the half-sandwich trisulfido complex of tungsten with silver ions: Synthesis of a cyanide-bridged helical polymer {[(eta(5)-C5Me5)WS3](2)Ag-3(CN)}(infinity) and a cyclic cluster [(eta(5)-C5Me5)WS3Ag](4)
Jp. Lang et K. Tatsumi, Aggregation of the half-sandwich trisulfido complex of tungsten with silver ions: Synthesis of a cyanide-bridged helical polymer {[(eta(5)-C5Me5)WS3](2)Ag-3(CN)}(infinity) and a cyclic cluster [(eta(5)-C5Me5)WS3Ag](4), INORG CHEM, 38(6), 1999, pp. 1364
An unusual cyanide-bridged helical polymer {[(eta(5)-C5Me5)WS3](2)Ag-3(CN)}
(infinity) (1) was obtained from the reaction between (PPh4)[(eta(5)-C5Me5)
WS3] and AgCN, which also gave a trace amount of an octanuclear cluster [(e
ta(5)-C5Me5)WS3Ag](4) (2). The latter cluster 2 was prepared in high yield
from the reaction of (PPh4)[(eta(5)-C5Me5)WS3] with [Ag(CH3CN)(4)](PF6).