Aggregation of the half-sandwich trisulfido complex of tungsten with silver ions: Synthesis of a cyanide-bridged helical polymer {[(eta(5)-C5Me5)WS3](2)Ag-3(CN)}(infinity) and a cyclic cluster [(eta(5)-C5Me5)WS3Ag](4)

Authors
Lang, JP Tatsumi, K
Citation
Jp. Lang et K. Tatsumi, Aggregation of the half-sandwich trisulfido complex of tungsten with silver ions: Synthesis of a cyanide-bridged helical polymer {[(eta(5)-C5Me5)WS3](2)Ag-3(CN)}(infinity) and a cyclic cluster [(eta(5)-C5Me5)WS3Ag](4), INORG CHEM, 38(6), 1999, pp. 1364
Citations number
39
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
6
Year of publication
1999
Database
ISI
SICI code
0020-1669(19990322)38:6<1364:AOTHTC>2.0.ZU;2-G
Abstract
An unusual cyanide-bridged helical polymer {[(eta(5)-C5Me5)WS3](2)Ag-3(CN)} (infinity) (1) was obtained from the reaction between (PPh4)[(eta(5)-C5Me5) WS3] and AgCN, which also gave a trace amount of an octanuclear cluster [(e ta(5)-C5Me5)WS3Ag](4) (2). The latter cluster 2 was prepared in high yield from the reaction of (PPh4)[(eta(5)-C5Me5)WS3] with [Ag(CH3CN)(4)](PF6).