Synthesis and spectroscopic properties of tetranuclear Re(I)(CO)(4)Cl complexes with tetracyanoethylene and tetracyanoquinodimethane as bridging ligands

Authors
Leirer, M Knor, G Vogler, A
Citation
M. Leirer et al., Synthesis and spectroscopic properties of tetranuclear Re(I)(CO)(4)Cl complexes with tetracyanoethylene and tetracyanoquinodimethane as bridging ligands, INORG CH C, 2(3), 1999, pp. 110-112
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
3
Year of publication
1999
Pages
110 - 112
Database
ISI
SICI code
1387-7003(199903)2:3<110:SASPOT>2.0.ZU;2-F
Abstract
The complexes {[Re-1(CO)(4)Cl](4)(mu-TCNX)} with TCNX = tetracyanoethylene and tetracyanoquinodimethane were prepared and characterized spectroscopica lly. Both compounds show Re(I) to TCNX metal-to-ligand charge transfer abso rptions in the near-infrared region. (C) 1999 Elsevier Science S.A. All rig hts reserved.