RAMAN-SPECTROSCOPIC MONITORING OF OXYGEN CLATHRATE HYDRATE FORMATION FROM MICROPOROUS AMORPHOUS SOLID WATER

Authors
HALLBRUCKER A
Citation
A. Hallbrucker, RAMAN-SPECTROSCOPIC MONITORING OF OXYGEN CLATHRATE HYDRATE FORMATION FROM MICROPOROUS AMORPHOUS SOLID WATER, Journal of the Chemical Society. Faraday transactions, 90(2), 1994, pp. 293-295
Citations number
10
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
90
Issue
2
Year of publication
1994
Pages
293 - 295
Database
ISI
SICI code
0956-5000(1994)90:2<293:RMOOCH>2.0.ZU;2-8
Abstract
The O-2 stretching vibration of O-2 adsorbed by vapour-deposited amorp hous solid water, after crystallization of amorphous to cubic ice, and after formation of oxygen clathrate hydrate, has been studied by Rama n spectroscopy: its peak maximum is shifted increasingly to lower freq uency and evidence is given that only the large cages of the clathrate hydrate structure are occupied by O-2 molecules.