The electronic bandstructure of strained Ga1-xInxN wells between barriers o
f GaN is found to exhibit an unusual Stark ladder controlled mainly by the
piezoelectric dipole across the strained layer. In luminescence and reflect
ion spectroscopy four distinct steps including a strong redshift with respe
ct to the thin film band gap are identified. Huge piezoelectric fields F le
ss than or equal to 1 MV/cm are derived directly from Franz-Keldysh oscilla
tions and interband transitions between carriers originating on opposite si
des of the well. For the largest strain and electric field, a Stark-like la
dder is identified. This provides important details for the interpretation
of the electronic band structure in group-Ill nitride heterostructures.