Study of a bimolecular annihilation process for coarsening reactants

Citation
Am. Lacasta et al., Study of a bimolecular annihilation process for coarsening reactants, J CHEM PHYS, 110(13), 1999, pp. 6458-6462
Citations number
26
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
110
Issue
13
Year of publication
1999
Pages
6458 - 6462
Database
ISI
SICI code
0021-9606(19990401)110:13<6458:SOABAP>2.0.ZU;2-6
Abstract
We consider the spatio-temporal behavior of the A+B --> 0 bimolecular react ion in a system where both reactants tend to segregate into separated phase s. Our study is based on the numerical solution of a pair of reaction-diffu sion equations appropriate to capture the underlying coarsening dynamics. T he interplay between reaction and coarsening leads to a complex pattern of reactants spatial distribution. At short/intermediate times two distinctive dynamical regimes are seen in the decay of overall concentration and dropl et number and the behavior of droplet radii. (C) 1999 American Institute of Physics. [S0021-9606(99)50911-2].