Authors
Citation
Mn. Khan, Effect of CH3CN-H2O and CH3CN solvents on rate of reaction of phthalimide with piperidine, J PHYS ORG, 12(3), 1999, pp. 187-193
Citations number
31
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
ISSN journal
08943230
→ ACNP
Volume
12
Issue
3
Year of publication
1999
Pages
187 - 193
Database
ISI
SICI code
0894-3230(199903)12:3<187:EOCACS>2.0.ZU;2-X
Abstract
Pseudo-first-order rate constants (k(obs)) for the reaction of piperidine w
ith phthalimide vary linearly with the total concentration of piperidine ([
Pip](T)) at a constant content of CH3CN in H2O-CH3CN solvents within the CH
3CN content range 2-80 % (v/v). The change in k(obs), with the change in [P
ip](T) at 100% (v/v) CH3CN obeys the relationship k(obs) = Psi [Pip](T)(2)/
(1 + Phi [Pip](T)). Copyright (C) 1999 John Wiley & Sons, Ltd.