For the first time registration of high-resolution soft x-ray emission and
atomic data. calculations of hollow-atom dielectronic satellite spectra of
highly charged nitrogen have been performed. Double-electron charge-exchang
e processes from excited stares are proposed for the formation of autoioniz
ing levels nln'l' in high-intensity laser-produced plasmas. when field-ioni
zed ions penetrate into the residual gas. Good agreement is found between t
heory and experiment. Plasma spectroscopy with hollow ions is proposed and
a temperature diagnostic for laser-produced plasmas in the long-lasting rec
ombining regime is developed.