The results of photoluminescence studies on hydrogen-related centres create
d in thermal treated silicon are reported. An account is given of the optic
al, electronic and structural characteristics of the defects obtained from
uniaxial stress, magnetic field and temperature-dependence measurements and
from isotope substitution. It is shown that most of the centres create an
acceptor state ( - /0) in the upper half of the band gap and that their exc
ited electronic states can be accounted for within the effective mass appro
ximation. (C) 1999 Elsevier Science S.A. All rights reserved.