The phonon spectrum for isolated nanoparticles is expected to become discre
te with a gap opening up at very low frequencies. In this paper we investig
ate the effect of the modified phonon spectrum on the relaxation of closely
spaced electronic levels. We compare the results for nanoparticles with th
ose for larger (similar to mu m) size particles with the same crystal struc
ture. (C) 1999 Elsevier Science B.V. All rights reserved.