DIPHENYLPHOSPHINOMETHANIDE COMPLEXES OF CHROMIUM(II) AND SAMARIUM(III) - PREPARATION AND CHARACTERIZATION OF THE DINUCLEAR ](MU-CL)[MU-C(H)(PPH(2))(2)][CR(PH(2)PC(H)PPH(2))] AND MONONUCLEAR PSEUDO-ALLYLIC SM[ETA(3)-PH(2)PC(H)PPH(2)](3)

Authors
HAO SK SONG JI AGHABOZORG H GAMBAROTTA S
Citation
Sk. Hao et al., DIPHENYLPHOSPHINOMETHANIDE COMPLEXES OF CHROMIUM(II) AND SAMARIUM(III) - PREPARATION AND CHARACTERIZATION OF THE DINUCLEAR ](MU-CL)[MU-C(H)(PPH(2))(2)][CR(PH(2)PC(H)PPH(2))] AND MONONUCLEAR PSEUDO-ALLYLIC SM[ETA(3)-PH(2)PC(H)PPH(2)](3), Journal of the Chemical Society, Chemical Communications, (2), 1994, pp. 157-158
Citations number
27
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
2
Year of publication
1994
Pages
157 - 158
Database
ISI
SICI code
0022-4936(1994):2<157:DCOCAS>2.0.ZU;2-3
Abstract
Reaction of lithium bis(diphenylphosphino)methanide with CrCl2(thf)(2) and SmCl3(thf)(3) led to the formation of an unprecedented dinuclear mixed-coordination complex ](mu-Cl)[mu-C(H)(PPh(2))(2)][Cr{Ph(2)PC(H)P Ph(2)}] 1 and mononuclear Sm[eta(3)-Ph(2)PC(H)PPh(2)](3) 2, respective ly.