INSERTION OF A TRANSITION-METAL FRAGMENT INTO A HEPTAANTIMONIDE(3-) ANION - SYNTHESIS AND STRUCTURE OF [SB7MO(CO)(3)](3-)

Authors
BOLLE U TREMEL W
Citation
U. Bolle et W. Tremel, INSERTION OF A TRANSITION-METAL FRAGMENT INTO A HEPTAANTIMONIDE(3-) ANION - SYNTHESIS AND STRUCTURE OF [SB7MO(CO)(3)](3-), Journal of the Chemical Society, Chemical Communications, (2), 1994, pp. 217-219
Citations number
47
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
2
Year of publication
1994
Pages
217 - 219
Database
ISI
SICI code
0022-4936(1994):2<217:IOATFI>2.0.ZU;2-Z
Abstract
Reaction of Na2Sb7 with Mo(bipy)(CO)(4) (bipy = bipyridyl) and 2,2,2-c rypt(4,7,13, ,21,24-hexaoxa-1,10-diazobicyclo[8.8.8]hexacosane) in eth ylenediamine results in the formation of [Na(2,2,2-crypt)](3) [Sb7Mo(C O)(3)], whose structure has been determined crystallographically.