The essential oils of Ocimum canum, O. gratissimum and O. minimum grown in
S. Tome, where they are used in Traditional Medicine mainly as febrifuge an
d for the treatment of respiratory diseases, were investigated. The essenti
al oils were obtained from the aerial parts by hydrodistillation and subseq
uently analysed by GC, CC-MS and C-13-NMR. C-13-NMR spectroscopy proved to
be an important tool, which can be very useful in the identification of mos
t of the constituents. Major compounds in the volatile oil of O. gratissimu
m were thymol (48.1%) and p-cymene (12.5%). The essential oil of O. canum w
as characterized by its high content of trans-methyl cinnamate (79.7%), whe
reas the most important oil constituent of O. minimum was linalool (52.7%).