Kinetics of oxidation of iodides by manganese dioxide in organic media

Authors
Ivanov, AM Bobrovskaya, SD
Citation
Am. Ivanov et Sd. Bobrovskaya, Kinetics of oxidation of iodides by manganese dioxide in organic media, RUS J AP CH, 71(10), 1998, pp. 1710-1713
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
71
Issue
10
Year of publication
1998
Pages
1710 - 1713
Database
ISI
SICI code
1070-4272(199810)71:10<1710:KOOOIB>2.0.ZU;2-E
Abstract
The effect of the ratio of starting reagents and water on the oxidation of iodides of alkaline metals and ammonium by manganese dioxide in toluene and acetic acid was studied. The kinetics of these processes was analyzed, and the dependences of rate constants and limiting conversions on starting con centrations of each component were investigated. A conclusion is made regar ding the limiting stage of the process.