C-13 NMR study of solutions of carbonyl compounds in 1,2-propylene glycol

Authors
Balashov, AL Danov, SM Krasnov, VL Chernov, AY Kvashennikov, AI
Citation
Al. Balashov et al., C-13 NMR study of solutions of carbonyl compounds in 1,2-propylene glycol, RUS J AP CH, 71(10), 1998, pp. 1721-1725
Citations number
15
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
71
Issue
10
Year of publication
1998
Pages
1721 - 1725
Database
ISI
SICI code
1070-4272(199810)71:10<1721:CNSOSO>2.0.ZU;2-5
Abstract
Equilibrium mixtures formed in reactions of acetaldehyde, propionaldehyde, benzaldehyde, and acetone with 1,2-propylene glycol at 25 degrees C in the absence of catalyst were studied by C-13 NMR. The equilibrium constants of the reactions and the compositions of the equilibrium mixtures in relation to the content of the carbonyl compound were determined quantitatively.