Main features of polymerization mechanism of 2- and 4-vinylpyridines underthe action of allyl derivatives of chromium, tungsten, and molybdenum

Authors
Shibaev, LA Novakov, P Fedorova, LA Antonova, TA Klenin, SI Adler, HPJ Erusalimskii, BL
Citation
La. Shibaev et al., Main features of polymerization mechanism of 2- and 4-vinylpyridines underthe action of allyl derivatives of chromium, tungsten, and molybdenum, RUS J AP CH, 71(10), 1998, pp. 1802-1806
Citations number
5
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
71
Issue
10
Year of publication
1998
Pages
1802 - 1806
Database
ISI
SICI code
1070-4272(199810)71:10<1802:MFOPMO>2.0.ZU;2-U
Abstract
A general kinetic scheme describing the main features of polymerization of 2- and 4-vinylpyridine under the action of allyl derivatives of chromium(II I), tungsten(IV), and molybdenum(IV) is described. Structural transformatio ns of the macromolecule formed by polymerization of 4-vinylpyridine under t he action of tris-pi-allylchromium were studied as influenced by the monome r conversion.