A NOVEL OXIDATIVE REARRANGEMENT OF A PENTASUBSTITUTED PYRROLE THAN UNSATURATED HYDROXY GAMMA-LACTAM

Authors
PROCOPIOU PA HIGHCOCK RM
Citation
Pa. Procopiou et Rm. Highcock, A NOVEL OXIDATIVE REARRANGEMENT OF A PENTASUBSTITUTED PYRROLE THAN UNSATURATED HYDROXY GAMMA-LACTAM, Journal of the Chemical Society. Perkin transactions. I, (3), 1994, pp. 245-247
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
3
Year of publication
1994
Pages
245 - 247
Database
ISI
SICI code
0300-922X(1994):3<245:ANOROA>2.0.ZU;2-C
Abstract
Treatment of a pentasubstituted bromopyrrole with N-bromosuccinimide r esulted in a novel oxidative rearrangement involving insertion of oxyg en. debromination and migration of an isopropyl group to give -5-oxo-3 -(4-pyridyl)-1H-pyrrol-1-yl]propionitrile, an X-ray crystallographic s tructural determination of which is described.