Scanning tunneling microscopy (STM) was used to study the adsorption of oxy
gen on the PdAg(111) surface. Oxygen appears as dark holes of ca 40 pm dept
h, whereas palladium atoms appear as bright spots. By comparing consecutive
STM images, oxygen was found to occupy only palladium sites: the oxygen wa
s found to travel exclusively to and from the palladium atoms. The surface
concentration of oxygen was low under all the experimental conditions used,
as indicated by STM as well as Auger electron spectroscopy. (C) 1999 Elsev
ier Science B.V. All rights reserved.