Resin-bound anionically induced domino reactions; Synthesis of functionalized carbocyclic compounds

Citation
Hj. Gutke et D. Spitzner, Resin-bound anionically induced domino reactions; Synthesis of functionalized carbocyclic compounds, TETRAHEDRON, 55(13), 1999, pp. 3931-3936
Citations number
17
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
55
Issue
13
Year of publication
1999
Pages
3931 - 3936
Database
ISI
SICI code
0040-4020(19990326)55:13<3931:RAIDRS>2.0.ZU;2-Z
Abstract
The anionically induced Domino reaction of resin-bound Li-dienolate with an alpha-halo-alpha,beta-unsaturated ester gave the corresponding immobilized tricyclo[3.2.1.0(2,7)]octane, which can be olefinated or oxidized. The cyc les are cleaved from the resin by acid. (C) 1999 Elsevier Science Ltd. All rights reserved.