Dibenz[c,h]acridine receptors for dibutylmalonic acid. Decarboxylative catalytic activity

Authors
Mussons, ML Raposo, C de la Torre, MF Moran, JR Caballero, MC
Citation
Ml. Mussons et al., Dibenz[c,h]acridine receptors for dibutylmalonic acid. Decarboxylative catalytic activity, TETRAHEDRON, 55(13), 1999, pp. 4077-4094
Citations number
25
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
55
Issue
13
Year of publication
1999
Pages
4077 - 4094
Database
ISI
SICI code
0040-4020(19990326)55:13<4077:DRFDAD>2.0.ZU;2-E
Abstract
New molecular receptors with dibenz[c,h]acridine skeleton bearing functiona l groups complementary to malonic acids have been developed. Dibutylmalonic acid is bound in chloroform with Kass values between 10(2) and 10(5) M-1 v ia hydrogen-bonding interactions. The catalytic ability of several of these receptors in the decarboxylative reaction of this diacid has been investig ated. (C) 1999 Elsevier Science Ltd. All rights reserved.