Chromium (VI) adsorbed on SiO2/ZrO2, a new supported reagent for allylic oxidations

Authors
Baptistella, LHB Sousa, IMO Gushikem, Y Aleixo, AM
Citation
Lhb. Baptistella et al., Chromium (VI) adsorbed on SiO2/ZrO2, a new supported reagent for allylic oxidations, TETRAHEDR L, 40(14), 1999, pp. 2695-2698
Citations number
33
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
14
Year of publication
1999
Pages
2695 - 2698
Database
ISI
SICI code
0040-4039(19990402)40:14<2695:C(AOSA>2.0.ZU;2-P
Abstract
Zirconium (IV) oxide coated on the surface of silica gel was used to absorb Cr(VI) from acidic solutions. This material. in conjunction with t-butyl h ydroperoxide, proved to be very useful for allylic oxidations. promoting ve ry clean reactions, with high regioselectivity. (C) 1999 Elsevier Science L td. All rights reserved.